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Highlights

IRG1: Modification of Plasmonic Nanocrystals with Sterically-Encumbered Isocyanide Ligands
IRG1: Modification of Plasmonic Nanocrystals with Sterically-Encumbered Isocyanide Ligands
May 12, 2025
Big Idea: Growing Convergence Research, Harnessing the Data Revolution, Quantum Leap

IRG1: Modification of Plasmonic Nanocrystals with Sterically-Encumbered Isocyanide Ligands

Joshua Figueroa, Tod Pascal, Shaowei Li, Andrea Tao: UC San Diego

A recent study revealed that m-terphenyl isocyanide ligands have different orientations when bonded to gold and silver surfaces—vertical on gold and flat on silver. This finding is important as it helps understand how surface ligands affect the properties of plasmonic nanoparticles. The research could lead to the development of new types of patterned nanoparticles, which would facilitate new self-assembly techniques, bridging the gap between inorganic materials and proteins.
Novel Electronic Bands in a Supermoiré Lattice
Novel Electronic Bands in a Supermoiré Lattice
May 7, 2025
Big Idea: Quantum Leap

Novel Electronic Bands in a Supermoiré Lattice

Shih, Han (Rice), Khalaf (Harvard), Giustino, Robinson (Penn State), Li

Super-moiré patterns identified in WSe2 bilayer with large twist angles. While moiré superlattices in graphene and transition metal dichalcogenide (TMD) bilayers with small twist angles are known to exhibit flat bands and host exotic correlated phases, strong lattice reconstruction in these systems poses challenges. In contrast, large-angle bilayers are structurally robust but typically considered electronically decoupled. Here, we discover robust super-moiré patterns emerging near a large commensurate angle, combining the advantages of both regimes—structural stability with flat electronic bands. This work expands moiré twistronics and flat-band quantum physics into the large twist-angle regime.
Independently Tunable Flat Bands and Correlations in a Graphene Double Moiré
Independently Tunable Flat Bands and Correlations in a Graphene Double Moiré
May 7, 2025
Big Idea: Quantum Leap

Independently Tunable Flat Bands and Correlations in a Graphene Double Moiré

Tutuc, MacDonald, Zheng, Taniguchi, Watanabe (NIMS, Japan)

Novel double moiré system realized in a four-layer twist- controlled graphene structure. These double moiré twist-controlled structure goes beyond the single moiré structures generally investigated in twisted bilayer graphene or transition metal dichalecogenides. The results show that demonstrate that electronic confinement in multilayer graphene stacks can be compactly realized by changing the twist angles, in contrast to traditional band engineering that employ dissimilar materials. Furthermore, near the magic angle the flat bands host correlated insulators, which suggests that the proximity of one flat band does not suppress the correlated insulating states in the other flat band.
By exciting an ITO nanocrystal with near-infrared (NIR) light, we generate heat that can be passed from the nanocrystal to its environment. We have tracked this process using probes placed at a nanocrystal’s surface and in its surrounding solvent that show colorimetric changes on heating.
By exciting an ITO nanocrystal with near-infrared (NIR) light, we generate heat that can be passed from the nanocrystal to its environment. We have tracked this process using probes placed at a nanocrystal’s surface and in its surrounding solvent that show colorimetric changes on heating.
May 7, 2025
Big Idea: Growing Convergence Research, Quantum Leap

Converting Light into Heat using Plasmonic Metal Oxide Nanocrystals

Sean T. Roberts, Carlos R. Baiz, Delia J. Milliron, & Thomas M. Truskett

Metal Oxide nanocrystals that incorporate dopants (impurities) can display intense absorption bands known as localized surface plasmon resonances (LSPRs) that can transduce light into heat. Using a series of time-resolved measurements with femtosecond resolution together with a theoretical heat transfer model, we have quantified timescales over which tin-doped indium oxide (ITO) nanocrystals heat their environment following light absorption.
A Light-Dependent Synthetic Cortex
A Light-Dependent Synthetic Cortex
May 7, 2025
Big Idea: Understanding the Rules of Life

A Light-Dependent Synthetic Cortex

Ahmed Sihorwala, Unyime Effiong, and Brian Belardi. UT Austin

Here, we developed a method to generate a synthetic cortex at the membrane of synthetic cells upon blue light illumination. This is important since it allow us to control the mechanical properties of synthetic cells reversibly. When incorporated into a synthetic tissue, this method would enable mechanical patterning and defining the 3D morphology of tissue with light.
Figure: (a) Materials trends in the energetics of defect complexes involving a metal adatom (from an electrode) adsorbed on a chalcogen vacancy are studied. (b) These defects are present in many monolayer systems and are relevant to resistive switching applications. (c) We reveal chemical bonding principles that explain trends in defect energetics, and (d) develop models based on electronic structure to predict energetics.
Figure: (a) Materials trends in the energetics of defect complexes involving a metal adatom (from an electrode) adsorbed on a chalcogen vacancy are studied. (b) These defects are present in many monolayer systems and are relevant to resistive switching applications. (c) We reveal chemical bonding principles that explain trends in defect energetics, and (d) develop models based on electronic structure to predict energetics.
May 7, 2025
University of Texas at Austin

Understanding & Predicting Trends in Defect Energetics in Monolayer Transition Metal Dichalcogenides

Brian H. Lee, Jameela Fatheema, Deji Akinwande, Wennie Wang

In this study,we focus on the adsorption and desorption of metal adatoms, which can modulate the electrical resistivity by several orders of magnitude. We develop material-based relationships of the adsorp-tion energy with electronic and atomic structure descriptors by examining the effects of various transition-metal adsorbates on the surface of TMDs. Our results reveal that adsorption energies of transition metals exhibit consistent trends across different TMDs (MoS2, MoSe2, WS2, WSe2)and can be explained using simple descriptors of the atomic and electronic structure. We propose several models to describe this adsorption process, providing a deeper understanding of a crucial step in the resistive switching mechanism based on the formation and dissolution of point defects.
Materials-Based Control of Actin Bundling
Materials-Based Control of Actin Bundling
May 7, 2025
Big Idea: Understanding the Rules of Life

Materials-Based Control of Actin Bundling

UT Austin: Alvarado, Stachowiak, Truskett, Milliron, Rosales; RIT: Das

In nature, actin bundling is a key capability that enables cells to apply substantial forces to overcome obstacles. Similarly, in the design of actin-based materials, the ability to bundle semi-rigid filaments into bundles of higher rigidity is a key step toward building more complex architectures. For this reason, developing a toolbox for controlling bundling is an important goal of our IRG. The approaches we have developed for controlling the bundling of actin filaments on a microscopic level allow us to construct actin-based materials with tunable mechanical properties.
Arts+Sciences: A Collaborative Model
Arts+Sciences: A Collaborative Model
May 7, 2025
Big Idea: Growing Convergence Research

Arts+Sciences: A Collaborative Model

Virginia L. Montgomery, Artist in Residence & Risa Hartman, UT Austin

The artist residency program at the Center for Dynamics and Control of Materials enables artists to work with CDCM faculty to create contemporary art installations that demonstrate emerging science and technology, bringing fundamental concepts in science to the public in very tangible, engaging ways.
Top: Photo of the CREATE 2024 student cohort taken at the program’s capstone poster session in July 2024. Left: Perylenediimide dyes synthesized by CREATE student Paige Melancon. Bottom Left: CREATE seminar held in February 2025 featuring CDCM Seed investigator Wennie Wang. Bottom: CREATE student Burna Leao Souza pictured with her capstone poster.
Top: Photo of the CREATE 2024 student cohort taken at the program’s capstone poster session in July 2024. Left: Perylenediimide dyes synthesized by CREATE student Paige Melancon. Bottom Left: CREATE seminar held in February 2025 featuring CDCM Seed investigator Wennie Wang. Bottom: CREATE student Burna Leao Souza pictured with her capstone poster.
May 7, 2025
Big Idea: Future of Work at the Human-Technology Frontier

CREATE: Connecting Research and Education At TExas

Sean Roberts (UT Austin), Shawn Amorde (ACC), Purna Murthy (ACC)

Connecting Research and Education At TExas (CREATE) is a partnership program established between UT Austin and Austin Community College (ACC) whose goal is to increase retention of community college students in STEM. CREATE works to achieve this goal by building relationships between ACC students and UT Austin researchers through a fall/spring seminar series held at ACC that features UT faculty speakers and a 9-week summer research program that pairs ACC students with research mentors at UT Austin.
Structure models for Cs2Ni3S4 from experimental powder x-ray
diffraction refinements and calculated band structure.
The stacking direction of the nickel layers sandwiched between
double layers of cesium can be seen in (A) along with the stacking
direction along the c axis. The slightly distorted kagome lattice is
depicted in (B) with color-coded bond lengths. The square-planar Ni-S
coordination environment is shown in (C). The Fmmm (D)
and P63/mmc (E) band structure show the flat bands close to the
Fermi level.
Structure models for Cs2Ni3S4 from experimental powder x-ray diffraction refinements and calculated band structure. The stacking direction of the nickel layers sandwiched between double layers of cesium can be seen in (A) along with the stacking direction along the c axis. The slightly distorted kagome lattice is depicted in (B) with color-coded bond lengths. The square-planar Ni-S coordination environment is shown in (C). The Fmmm (D) and P63/mmc (E) band structure show the flat bands close to the Fermi level.
May 5, 2025
Big Idea: Quantum Leap

Accessing Bands with Extended Quantum Metric in Kagome Cs2Ni3S4 through Soft Chemical Processing

Leslie M Schoop and B. Andrei Bernevig

Flat bands have been associated with excoct effects in materials, such as strong correlations, superconductivity, or the fractional quantum Hall effect. In bulk materials they are difficult to be isolated form other electronic states. In addition, they are often at non-accessible energies. In this work, Schoop and Bernevig collaborated to access flat bands in a new material using soft-chemical modification of a known materials.