Researchers in the Wisconsin MRSEC have shown that depositing onto an alignment substrate creates better glass films that are anisotropic biaxially, meaning they are aligned in the plane of the substrate as well as out of plane. The in-plane orientation of the molecules affect how they interact with light and conduct electricity. In general, more alignment is better for applications ranging from flexible transistors to OLEDs to organic photovoltaics.
The UC San Diego team has achieved the assembly of checkerboard lattices from colloidal nanocrystals that harness the effects of multiple, coupled physical forces at disparate length scales (interfacial, interparticle, and intermolecular) and that do not rely on chemical binding. Colloidal Ag nanocubes were bi-functionalized with mixtures of hydrophilic and hydrophobic surface ligands and subsequently assembled at an air-water interface.
UC San Diego researchers developed and programmed cyanobacterial composite materials to remediate an organic dye pollutant.
Optical properties of plasmonic ITO nanocrystal gels, assembled by thermoreversible cobalt terpyridine links, were tuned systematically based on the size and doping concentration of the nanocrystals and length of the custom ligand molecules. Correlation of optical shifts upon assembly with nanocrystal spacing deduced by small angle X-ray scattering was used to develop a universal structure-property relationship that was validated by large-scale optical simulations on gels made using Brownian dynamics simulations.
UT Austin researchers developed synthetic multi-arm poly(ethylene glycol) (PEG) hydrogels with three different dynamic covalent linking chemistries. They exhibit non-monotonic flow curves under steady shear, with shear thickening behavior that depends on the crosslinking bond exchange kinetics and polymer concentration.
This study by UT Austin researchers demonstrates the rich electronic structures in large-angle twisted bilayer WSe2 exemplified by the formation of multiple mini-gaps near the valence band maximum. By tuning the commensurability, the moiré material properties and functionalities can be precisely engineered.
UT Austin MRSEC researchers show that ferroelectric polar domains formed in a twisted hexagonal boron nitride (t-hBN) substrate can modulate light emission from an adjacent semiconductor monolayer. The abrupt change in electrostatic potential across the domains produces an in-plane electric field (E-field) and leads to a remarkably large exciton Stark shift in the adjacent MoSe2 monolayer, previously only observable in p-n junctions created by the advanced e-beam lithography tools. Both the spectrum and spatial pattern of the light emission of the monolayer are periodically modulated by the remote moire potential imposed by the t-hBN substrate.
CDCM has designed and launched one of the few materials science podcasts available to the public. The first season will feature 6 episodes where the podcast host, Abbey Stanzione, interviews CDCM MRSEC faculty about their educational backgrounds, pathway into academia and their cutting edge materials science research.
THz emission spectroscopy developed at UIUC is used to investigate spin current generation in the antiferromagnetic metal FeRh under ultrafast laser excitation. The transient spin current in FeRh can be extracted from the emitted THz field. Developing viable platforms for the transduction between charge and spin current is crucial for spintronic based electronic devices. The Illinois MRSEC's work investigates FeRh as one such platform.
In February 2024, I-MRSEC investigator Daniel Shoemaker, grad student Emily Waite, and outreach coordinator Pamela Pena Martin taught 35 7th and 8th graders at Franklin STEAM Academy, a Champaign public middle school, about magnetism through a kit they developed, supported by the I-MRSEC and a grant from the APS Group on Magnetism and its Applications. This visit was part of an annual 7-week program that teaches materials science concepts through hands-on activities aimed to build interest and confidence in STEM.
