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Pushing the Limits of Topotactic Cycling Endurance  in Oxide Electrochemical Transistors
Pushing the Limits of Topotactic Cycling Endurance in Oxide Electrochemical Transistors
May 14, 2025
Big Idea: Growing Convergence Research

Pushing the Limits of Topotactic Cycling Endurance in Oxide Electrochemical Transistors

K. A. Stoerzinger (Seed), C. Leighton, V. E. Ferry (IRG-1)

Recent research on oxide electrochemical transistors from the UMN MRSEC has significantly improved their performance, particularly in cycling endurance. A collaboration led to record durability in ion-gel transistors using La0.5Sr0.5CoO3-d (LSCO), enhancing previous limits drastically. By applying operando FTIR spectroscopy, researchers gained insights into the factors affecting performance, such as humidity and device design. These advancements open up potential uses for LSCO in areas like thermal camouflage and thermoregulation.
(a) Odd active solids exhibit adaptive locomotion on a granular terrain. When interacting with an external environment, chiral active solids spontaneously undergo limit cycles of shape changes, which naturally lead to locomotion such as rolling and crawling. The robustness of the locomotion is rooted in an emergent feedback loop between the active solid and the environment, which is mediated by odd elastic deformations and stresses.
(a) Odd active solids exhibit adaptive locomotion on a granular terrain. When interacting with an external environment, chiral active solids spontaneously undergo limit cycles of shape changes, which naturally lead to locomotion such as rolling and crawling. The robustness of the locomotion is rooted in an emergent feedback loop between the active solid and the environment, which is mediated by odd elastic deformations and stresses.
May 14, 2025
Big Idea: Understanding the Rules of Life

Chiral active solids with life-like properties

IRG-2: Vitelli group

Researchers developed active solids made of centimeter-scale building blocks that can move and adapt in different environments. These prototypes show unique elasticity, which allows them to change their movement patterns and navigate various terrains effectively, similar to complex robotic systems. This study highlights the potential of these materials to link robotics and material science and suggests new ways to control dynamic systems in nature and technology.
(A) Suspension of fumed silica particles functionalized with dynamic covalent chemistry. (B) Training protocol and outcomes for different training velocities. (C & D) Trained-in resistance as function of training cycle and velocity.
(A) Suspension of fumed silica particles functionalized with dynamic covalent chemistry. (B) Training protocol and outcomes for different training velocities. (C & D) Trained-in resistance as function of training cycle and velocity.
May 14, 2025
Big Idea: Understanding the Rules of Life

Dense suspensions as trainable rheological metafluids

Heinrich Jaeger & Stuart Rowan (UChicago)

A recent study by Hojin Kim and Samantha Livermore shows that dense suspensions can be trained to respond differently to stress levels, similar to how living organisms train for better performance. By applying shear stress, these materials can develop “memories” that affect their mechanical properties, becoming either stiffer or softer with repeated impacts. This innovative approach suggests potential applications for materials that can adapt and change their viscosity or energy dissipation on demand.
Co-based metal-organic frameworks as spin liquid candidates
Co-based metal-organic frameworks as spin liquid candidates
May 14, 2025
Big Idea: Quantum Leap

Co-based metal-organic frameworks as spin liquid candidates

Prof. Yiying Wu, Jos Heremans, Nandini Trivedi, Yuanming Lu (OSU), Sara Haravifard (Duke)

Researchers have created a new cobalt-based metal-organic framework that shows potential for hosting a Kitaev spin liquid. This material features cobalt ions in a honeycomb arrangement, linked together by benzoquinone, which creates a special type of magnetic frustration. By adjusting the linkers' chemical composition, the strength of the magnetic interactions can be varied. While magnetization tests indicated antiferromagnetic interactions, no spin ordering was found at low temperatures, highlighting this framework's potential in exploring spin liquid physics.
Upper left: A schematic of the Kitaev honeycomb model and its Hamiltonian.
Upper right: a two-spin flip operator creates a pair of Majorana excitations 𝑚 in the ground state. Lower left: the single-spin-flip structure factor 𝑆_1 does not show features of the Majorana excitations. Lower right: the two-spin-flip structure factor 𝑆_2^𝑧 shows sharp features that reflect the dispersion relation of the Majoranas.
Upper left: A schematic of the Kitaev honeycomb model and its Hamiltonian. Upper right: a two-spin flip operator creates a pair of Majorana excitations 𝑚 in the ground state. Lower left: the single-spin-flip structure factor 𝑆_1 does not show features of the Majorana excitations. Lower right: the two-spin-flip structure factor 𝑆_2^𝑧 shows sharp features that reflect the dispersion relation of the Majoranas.
May 14, 2025
Big Idea: Quantum Leap, Harnessing the Data Revolution

Sharp signatures of fractionalized excitations in Kitaev spin liquids

Prof. Nandini Trivedi, The Ohio State University

Researchers have theoretically shown that distinct signs of Majorana excitations can be found in the Kitaev honeycomb model when a perpendicular magnetic field is applied. These unique features appear in what are called two-spin-flip excitations. The findings suggest that techniques like nonlinear THz spectroscopy could help detect these signatures in materials that are being studied as spin liquids. This work advances the understanding of quantum matter in these complex systems.
Figure 1. (a) Schematic of BV center in hBN (b) Regions of exfoliated hBN containing BV centers created by scanned Ga ion-irradiation are visible in  hBN exfoliated onto a microwave waveguide on top of the sample (c)  Optically detected magnetic resonance of BV centers showing expected linear dispersion (magnetic field perpendicular to the plane) (d) optically detected FMR of YIG employing relaxometry of BVs by magnons.
Figure 1. (a) Schematic of BV center in hBN (b) Regions of exfoliated hBN containing BV centers created by scanned Ga ion-irradiation are visible in hBN exfoliated onto a microwave waveguide on top of the sample (c) Optically detected magnetic resonance of BV centers showing expected linear dispersion (magnetic field perpendicular to the plane) (d) optically detected FMR of YIG employing relaxometry of BVs by magnons.
May 14, 2025
Big Idea: Quantum Leap

Quantum Sensing of Spin Dynamics Using Boron-Vacancy Centers in Hexagonal Boron Nitride

P. Chris Hammel, Fengyuan Yang (OSU), Jyoti Katoch, Simranjeet Singh (CMU)

A recent study showcased how boron-vacancy centers in hexagonal boron nitride can be used for quantum sensing. These defects allow for the detection of weak magnetic fields through their spin-sensitive light emissions. The researchers demonstrated the capability to optically detect specific magnetic wave behaviors in materials like yttrium iron garnet. This work positions boron-vacancy centers as a flexible tool for exploring various magnetic phenomena in new material systems.
Figure 1. (a) Atomically clean WTe2/CGT interface. (b) Left: Generation of nonequilibrium spin accumulation with an out-of-plane spin polarization (𝝈_𝒛), when a charge current (𝐽) is applied along the a-axis of WTe2. Right: Concept of unconventional UMR in heterostructures, i.e., change of longitudinal resistance (𝑅_𝑈𝑀𝑅) depending on the relative orientation of out-of-plane magnetization (𝒎_𝒛) and spin polarization (𝝈_𝒛). (c) A schematic showing the measurement configuration to read the out-of-plane magnetic state of CGT employing 2-point longitudinal resistance (𝑅_𝑥𝑥). (d) UMR signal measured with +/- current. The step-like change in 2-point 𝑅_𝑥𝑥  is due to UMR switching sign when the current is reversed, with symmetric and antisymmetric components shown (lower panel).
Figure 1. (a) Atomically clean WTe2/CGT interface. (b) Left: Generation of nonequilibrium spin accumulation with an out-of-plane spin polarization (𝝈_𝒛), when a charge current (𝐽) is applied along the a-axis of WTe2. Right: Concept of unconventional UMR in heterostructures, i.e., change of longitudinal resistance (𝑅_𝑈𝑀𝑅) depending on the relative orientation of out-of-plane magnetization (𝒎_𝒛) and spin polarization (𝝈_𝒛). (c) A schematic showing the measurement configuration to read the out-of-plane magnetic state of CGT employing 2-point longitudinal resistance (𝑅_𝑥𝑥). (d) UMR signal measured with +/- current. The step-like change in 2-point 𝑅_𝑥𝑥 is due to UMR switching sign when the current is reversed, with symmetric and antisymmetric components shown (lower panel).
May 14, 2025
Big Idea: Quantum Leap

Discovery of a New Type of Magnetoresistance

Simranjeet Singh (CMU), Jyoti Katoch (CMU), Jinwoo Hwang (OSU)

A new type of magnetoresistance called unidirectional magnetoresistance (UMR) has been discovered in a study that combines a topological semimetal (WTe₂) with a ferromagnetic semiconductor (Cr₂Ge₂Te₆). This phenomenon involves changes in resistance linked to magnetization reversal and spin interactions. The findings highlight how the unique properties of these materials can create distinct resistance states, which could be valuable for developing more advanced magnetic memory devices.
A responsive living material prepared by diffusion reveals extracellular enzyme activity of cyanobacteria
A responsive living material prepared by diffusion reveals extracellular enzyme activity of cyanobacteria
May 12, 2025
Big Idea: Recyclable Plastics and Alternative Materials, Synthetic Materials Biology, Understanding the Rules of Life

A responsive living material prepared by diffusion reveals extracellular enzyme activity of cyanobacteria

Lisa Tang, Nathan Soulier, Rebecca Wheeler, Jonathan K. Pokorski, James W. Golden, Susan S. Golden, Jinhye Bae: UC San Diego

One of the research goals of UCSD MRSEC IRG2 included developing shape-shifting materials driven by asymmetric forces. In a recent effort, the MRSEC team demonstrated an ELM capable of shape-shifting driven by both a temperature stimulus and enzymatic mediated partial degradation of the composite material.
IRG1: Modification of Plasmonic Nanocrystals with Sterically-Encumbered Isocyanide Ligands
IRG1: Modification of Plasmonic Nanocrystals with Sterically-Encumbered Isocyanide Ligands
May 12, 2025
Big Idea: Growing Convergence Research, Harnessing the Data Revolution, Quantum Leap

IRG1: Modification of Plasmonic Nanocrystals with Sterically-Encumbered Isocyanide Ligands

Joshua Figueroa, Tod Pascal, Shaowei Li, Andrea Tao: UC San Diego

A recent study revealed that m-terphenyl isocyanide ligands have different orientations when bonded to gold and silver surfaces—vertical on gold and flat on silver. This finding is important as it helps understand how surface ligands affect the properties of plasmonic nanoparticles. The research could lead to the development of new types of patterned nanoparticles, which would facilitate new self-assembly techniques, bridging the gap between inorganic materials and proteins.
Novel Electronic Bands in a Supermoiré Lattice
Novel Electronic Bands in a Supermoiré Lattice
May 7, 2025
Big Idea: Quantum Leap

Novel Electronic Bands in a Supermoiré Lattice

Shih, Han (Rice), Khalaf (Harvard), Giustino, Robinson (Penn State), Li

Super-moiré patterns identified in WSe2 bilayer with large twist angles. While moiré superlattices in graphene and transition metal dichalcogenide (TMD) bilayers with small twist angles are known to exhibit flat bands and host exotic correlated phases, strong lattice reconstruction in these systems poses challenges. In contrast, large-angle bilayers are structurally robust but typically considered electronically decoupled. Here, we discover robust super-moiré patterns emerging near a large commensurate angle, combining the advantages of both regimes—structural stability with flat electronic bands. This work expands moiré twistronics and flat-band quantum physics into the large twist-angle regime.