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Program Highlights

Absence of E2g Nematic Instability and Dominant A1g Response in Kagome Metal CsV3Sb5

Electronic nematicity, the spontaneous breaking of crystalline rotational symmetry, has been discovered in several strongly correlated electronic systems, including high Tc superconductors. Recently, several studies have suggested that the charge density wave in the kagome superconductor CsV3Sb5 breaks rotational symmetry—an intriguing possibility, as it would be a rare example of “three-state Potts nematicity,” in which there are three possible orientations in a hexagonal lattice. Here, MRSEC researchers at the University of Washington report that  CsV3Sb5 is probably not nematic, but it is very sensitive to isotropic strain.

Ferrimagnetic CuCr2Se4 Nanocrystals with Strong Room-Temperature Magnetic Circular Dichroism

Magnetic materials are vital in technologies from spintronics to biomedicine. Coupling magnetism with optical responses broadens their utility to sensing, magneto-optical memory, and optical isolation.  Chromium chalcogenide spinels display particularly rich magnetism and magneto-optical properties. Colloidal nanocrystals offer routes to solution-processing, heterointegration, and property modulation through size, shape, or heterostructure control, but many chalcogenide spinels have never been synthesized at the nanoscale, and little control over size or morphology has been demonstrated.

CAMM Partners with ORNL to Host “Neutron Day”

UTK-MRSEC The Center for Advanced Materials & Manufacturing partnered with Oak Ridge National Laboratory to host the inaugural "Neutron Day," an event designed to deepen collaboration and foster interdisciplinary research connections.

Quantum Materials and Machine Learning Workshop

The recent Quantum Materials and Machine Learning Workshop brought together 22 invited speakers and in total 50 graduate students, postdoc, faculty attendees from 18 different institutions for an intensive exploration of cutting-edge developments at the intersection of quantum physics, materials science, and machine learning. The program featured established researchers alongside three postdoctoral fellows, fostering meaningful dialogue between different career stages.

Peptide ‘Bundlemer’ Building Blocks for New Liquid Crystal Formation

The CHARM team successfully used computational design to produce new, non-natural peptide molecules that self-assemble into discrete nanoparticles that are 2 nm in diameter and 4 nm in length. The new nanoparticles, examples of the class of protein structure call coiled coils, result in exciting new self-assembly behavior with potential to impact materials technology.

FORGES: Foundations of Outreach for Recruitment of Great Engineers & Scientists

CHARM partnered with academic departments and local industry at the University of Delaware to provide experiential exposure to STEM fields, collegiate lab settings, and industry settings and equipment to students historically underrepresented in STEM. Students visited one department or industry partner for one day per week, for 7 weeks.

Hybrid Terahertz Emitter for Pulse Shaping and Chirality Control

The University of Delaware MRSEC team has developed and implemented a hybrid THz radiation source that combines a conventional III-V semiconductor-based photoconductive antenna with a spintronic emitter integrated into a single device. This hybrid emitter leverages the unique properties of both components: the wavelength sensitivity of the semiconductor material and the wavelength insensitivity of the spintronic heterostructure. 

IRG-1 Skyrmion Transitions in Co8Zn8Mn4 at Room Temperature

Intellectual merit:  Magnetic skyrmions are topologically-protected spin textures that manifest in certain noncentrosymmetric ferromagnets under the right conditions of temperature and field.

IRG-3: Resilient Multiphase Soft Materials

Intellectual merit: Biomolecular assembly processes involving a competition between specific intermolecular interactions and thermodynamic phase instability have been implicated in a number of pathological states and technological applications of biomaterials.

IRG-2: Light-Switchable and Self-Healable Polymer Electrolytes

Intellectual merit: Chemically dissimilar polymers are rarely miscible due to an entropy of mixing that scales as 1/N, where N is the degree of polymerization. As a consequence, the compatibilization of immiscible polymer blends presents a major challenge to plastics recycling efforts.

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