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Persistence of Small Polarons in Doped Bismuthate Superconductors

  • Bismuthates like (Ba1-xKxBiO3) BKBO host high-Tc superconductivity via doping a charge-density-wave insulating phase.
  • While electron-phonon (e-ph) coupling is proposed to play a key role, the bismuthate normal state is anomalous and poorly understood. 
  • Researchers from IRGs 1, 2, and the Paul-Sherre Institute combined resonant inelastic x-ray and neutron total scattering techniques with advanced modeling to address this problem.
  • The team found that the doped system hosts short-range structural distortions of the lattice with a sizable e-ph coupling deep into the material’s metallic phase.
  • These findings demonstrate that BKBO’s metallic phase is an anomalous and highly sought after bipolaronic liquid.