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Deformation and Orientational Order of Chiralmembranes with Free Edges
Deformation and Orientational Order of Chiral membranes with Free Edges
Nov 29, 2021
Brandeis University

Deformation and Orientational Order of Chiral membranes with Free Edges

L. Ding,  R. A. Pelcovits,  T. R. Powers: Brown University Z. Dogic: Brandeis University, UCSB  

Producing self-assembled structures of prescribed limited size and shape is a major challenge in nanoscience. A major achievement of the MRSEC was to elucidate a new chirality-based mechanism that leads to self-limiting assembly of colloidal rafts.
Confinement Controls the Bend Instability of Three-Dimensional Active Liquid Crystals
Confinement Controls the Bend Instability of Three-Dimensional Active Liquid Crystals
Nov 29, 2021
Brandeis University

Confinement Controls the Bend Instability of Three-Dimensional Active Liquid Crystals

G. Duclos, A. Baskaran: Brandeis University Z. Dogic: Brandeis University, UCSB

Here, three IRG2 PP developed a combination of experiments with 3D active fluids confined in microfluidic channels and a minimal hydrodynamic model to show that size of the channel determines the emergent lengthscale of the growing deformations. These findings will advance our understanding of active nemato-hydrodynamics and the pathways to 3D active turbulence at low Reynolds number.
During fibrosis, collagen fibers become denser and aligned.  Engineered fibrous matrices now respond to mechanical loading to densify and align fibers through inter-fiber adhesion.
During fibrosis, collagen fibers become denser and aligned. Engineered fibrous matrices now respond to mechanical loading to densify and align fibers through inter-fiber adhesion.
Aug 3, 2021
University of Pennsylvania

Fibrous Networks in Liver Fibrosis

Rebecca Wells, Jason Burdick, Vivek Shenoy, University of Pennsylvania

Animal  tissues are composed of cells attached to either the surface of a fibrous network called a basement membrane or embedded within a 3D extracellular or interstitial matrix. As the disease liver fibrosis progresses, the extracellular fibrous networks become denser and more aligned. These physical changes lead to different mechanical properties and structures to which cells are exquisitely sensitive. To better understand the pathological effects of these changes during fibrosis on cells, we have engineered material platforms that mimic the extracellular matrix in tissue health and disease. As an example, we have fabricated fibrous materials that have varied mechanical properties and fiber densities when mechanically loaded due to the chemical adhesion between fibers, similar to natural extracellular matrix (see Figure).
The molecular clutch model (top) of mechanotransduction explains the effect of matrix viscoelasticity on cell spreading. Simulations predict optimal cell spreading when the timescale for stress relaxation (τs) is similar to the clutch binding timescale (τb).
The molecular clutch model (top) of mechanotransduction explains the effect of matrix viscoelasticity on cell spreading. Simulations predict optimal cell spreading when the timescale for stress relaxation (τs) is similar to the clutch binding timescale (τb).
Aug 3, 2021
University of Pennsylvania

Effects of extracellular matrix viscoelasticity on cellular behavior

Paul Janmey, Vivek Shenoy, University of Pennsylvania

Linearly elastic elastomers coated with matrix proteins are widely used to assess the role of stiffness. Such experiments are often assumed to reproduce the effect of the mechanical environment experienced by cells in vivo. However, tissues and the extracellular matrix (ECM) are not linearly elastic materials. They exhibit far more complex mechanical behaviors. These behaviors include viscoelasticity, as well as mechanical plasticity, and nonlinear elasticity. Our theoretical and experimental work has revealed that matrix viscoelasticity regulates fundamental cell processes and can promote behaviors – such as proliferation, motility and spreading – that are not observed with elastic hydrogels in both two- and three-dimensional culture microenvironments.
(Top) Experimental setup (left) and map of creep strains within the sandpile measured via Diffusive Wave Spectroscopy (DWS) (right). At the moment of preparation and up to 11 days after pouring (right), spatially-heterogeneous creeping motions appear within the pile. (Bottom) Heat perturbations reset the creep rate and the timescale of relaxation (left) while tapping reduces the creep rate, and confines deformation to the free surface (right)
(Top) Experimental setup (left) and map of creep strains within the sandpile measured via Diffusive Wave Spectroscopy (DWS) (right). At the moment of preparation and up to 11 days after pouring (right), spatially-heterogeneous creeping motions appear within the pile. (Bottom) Heat perturbations reset the creep rate and the timescale of relaxation (left) while tapping reduces the creep rate, and confines deformation to the free surface (right)
Aug 3, 2021
University of Pennsylvania

The Perpetual Fragility of Creeping Hillslopes

Douglas J. Jerolmack, Paulo E. Arratia, & Robert A. Riggleman, University of Pennsylvania

Soil is a highly disordered granular material. Slow soil deformation (creep) controls the shape of hills in the natural landscape, and is a precursor of catastrophic landsliding. Our work demonstrates a surprising observation: an apparently static sandpile, sitting on a table, is actually alive with motion. We study a 3D granular heap, confined by walls and prepared by pouring. Via Diffusive Wave Spectroscopy (DWS), we observe the existence of spatially-heterogeneous micro-deformations that decay in size and frequency as time progresses but persist up to 11 days after the preparation of the system; the heap relaxes. We find that this relaxation can be enhanced  (overaged) or reversed (rejuvenated) by tuning the types of disturbances applied to system.
Surface Modification of Black Phosphorus with Group 13 Lewis Acids for Ambient Protection and Electronic Tuning
Surface Modification of Black Phosphorus with Group 13 Lewis Acids for Ambient Protection and Electronic Tuning
Jun 3, 2021
Big Idea: Quantum Leap

Surface Modification of Black Phosphorus with Group 13 Lewis Acids for Ambient Protection and Electronic Tuning

Alexandra Velian and Mo Li Molecular Engineering Materials Center (MEM-C) University of Washington, Seattle

We have developed a solution-phase protocol to modify the Lewis basic surface of few-layer black phosphorus (bP) using commercially available Lewis acids, and demonstrated its effectiveness at providing outstanding ambient stability and tuning of electronic properties.
Tunable Correlated and Topological States in Twisted Graphene Multilayers
Tunable Correlated and Topological States in Twisted Graphene Multilayers
Jun 3, 2021
Big Idea: Quantum Leap

Tunable Correlated and Topological States in Twisted Graphene Multilayers

David Cobden, Xiaodong Xu and Matthew Yankowitz Molecular Engineering Materials Center (MEM-C) University of Washington, Seattle

Stacking various atomically-thin crystals on top of one another can strongly modify their overall properties. When two materials are stacked with a twist angle, a geometric interference pattern (a moiré pattern) emerges. At special twist angles, the moiré pattern can result in new electronic states dominated by strong correlations between electrons.
PCCM Holiday Lecture 2020: "A Materials Wonderland: A Celebration of How Materials Science Make Our Holidays Fun
PCCM Holiday Lecture 2020: "A Materials Wonderland: A Celebration of How Materials Science Make Our Holidays Fun
May 18, 2021
Princeton University

Holiday Lecture 2020: A Materials Wonderland

PCCM celebrated its annual Holiday Lecture 2020: A Materials Wonderland: A Celebration of How Materials Science Make Our Holidays Fun with PCCM faculty, research members and others providing (virtual) materials science presentations. The audience helped with experiments and demonstrations from their homes. 426 families registered, some with multiple children (tuning from all over the world), resulting in ~1,000 attendees!
A team led by Princeton physicists discovered a surprising quantum phenomenon in an atomically thin insulator made of tungsten ditelluride. The results suggest the formation of completely new types of quantum phases previously hidden in insulators. Image source: Image designed by Kai Fu for the Wu Lab, Princeton University
A team led by Princeton physicists discovered a surprising quantum phenomenon in an atomically thin insulator made of tungsten ditelluride. The results suggest the formation of completely new types of quantum phases previously hidden in insulators. Image source: Image designed by Kai Fu for the Wu Lab, Princeton University
May 18, 2021
Big Idea: Quantum Leap

Discovery of Intrinsic Landau Quantization in an Insulator

P. Wang1*, G. Yu1*, Y. Jia1*, M. Onyszczak1, F. A. Cevallos1, S. Lei1, S. Klemenz1, K. Watanabe2, T. Taniguchi2, R. J. Cava1, L. M. Schoop1, S. Wu1, Nature 589, 225–229 (2021) 1 Princeton University, USA 2National Institute for Materials Science, Tsukuba, Japan

In a surprising discovery, Princeton physicists have observed an unexpected quantum behavior in an insulator made from a material called tungsten ditelluride. This phenomenon, known as quantum oscillation, is typically observed in metals rather than insulators, and its discovery offers new insights into our understanding of the quantum world. The findings also hint at the existence of an entirely new type of quantum particle.
Multi-qubit Entanglement in a Quantum Network
Multi-qubit Entanglement in a Quantum Network