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Highlights

Apr 4, 2019
Materials Research Science and Engineering Center at UCSB

DNA-inspired switchable synthetic morphologies

Ren, Knight, van Ravensteijn, Kohl, Bou Zerdan, Li, Lunn, Abdilla, Qiao, Hawker UCSB

A novel strategy offers new opportunities to program dynamic behaviors in synthetic polymeric systems, leading to scalable synthesis of “smart” nanosystems. Novel PMMA strand-exchange, inspired by DNA nanotechnologies, enables dynamic behaviors in synthetic polymeric systems. Polymer assembly produces spherical or wormlike micelles, which can be reversibly switched between different morphologies.
During the 2017 Capstone week, teachers shared their education modules with their cohort (top), learned about agriculturally important coffee (bottom left), and about the impact of climate change on coral reefs (bottom right).
During the 2017 Capstone week, teachers shared their education modules with their cohort (top), learned about agriculturally important coffee (bottom left), and about the impact of climate change on coral reefs (bottom right).
An image acquired on a prototype ultrafast camera capable of acquiring images in 200 microseconds. The image shows a metallic glass nanowire, heated inside the microscope into the liquid state so the atoms start to move.
An image acquired on a prototype ultrafast camera capable of acquiring images in 200 microseconds. The image shows a metallic glass nanowire, heated inside the microscope into the liquid state so the atoms start to move.
Dec 20, 2018
Wisconsin Materials Research Science and Engineering Center

An Ultrafast Camera for Transmission Electron Microscopy

Paul M. Voyles, University of Wisconsin-Madison

Current TEM cameras acquire images in a few milliseconds. The new camera will ultimately acquire images in just 8 microseconds, which will enable researchers to study fast processes in materials like atoms rearranging in a flowing liquid and to probe the smallest structures in materials. 
MRSEC REU student, Nicole Trometer, is a co-author in this study.
MRSEC REU student, Nicole Trometer, is a co-author in this study.
Dec 15, 2018
Next Generation Materials for Plasmonics and Organic Spintronics (2011)

Synchronized Terahertz Plasmons in Ultra-Thin Membrane GaN HEMT Arrays

J. Encomendero, M. Zhu, Debdeep Jena & Grace Xing; Cornell. M. Trometer; University of Florida. H. Condori, A. Chanana, A. Nahata & B. Sensale-Rodriguez; University of Utah

Promising a myriad of transformative applications in various fields such as communications, security, chemical & biological sensing, and astronomy, terahertz (THz) technology is a very promising technological field. In order to realize efficient THz systems, development of active devices, such as detectors and emitters is required.
(a) Schematic and SEM image of a colloidal Au nanorod (NR) trimer and (b) its s- (red) and p- (black) polarization dependent darkfield scattering spectra. The intensity is normalized by the peak intensity of the s-polarization spectrum. (c) Electromagnetic simulations show a circulating pattern of electric dipoles in the electric field map (top) indicative of the enhanced magnetic field within the center of the NR trimer (bottom). (d) Axial displacement of assembled Au NRs creates “left-handed” (not shown) and “right-handed” 2D enantiomers. The substrate and direction of illumination breaks symmetry in three dimensions, known as extrinsic chirality, creating a chiroptical response.
(a) Schematic and SEM image of a colloidal Au nanorod (NR) trimer and (b) its s- (red) and p- (black) polarization dependent darkfield scattering spectra. The intensity is normalized by the peak intensity of the s-polarization spectrum. (c) Electromagnetic simulations show a circulating pattern of electric dipoles in the electric field map (top) indicative of the enhanced magnetic field within the center of the NR trimer (bottom). (d) Axial displacement of assembled Au NRs creates “left-handed” (not shown) and “right-handed” 2D enantiomers. The substrate and direction of illumination breaks symmetry in three dimensions, known as extrinsic chirality, creating a chiroptical response.
Nov 2, 2018
UPENN Materials Research Science and Engineering Centers

Plasmonic Optical and Chiral Optical Responses of Self-Assembled Gold Nanorod Equilateral Trimers

Cherie Kagan (ESE), Chris Murray (Chemistry and MSE), Nader Engheta (ESE) all from the University of Pennsylvania MRSEC (IRG 3)

The groups of Kagan, Murray, and Engheta in IRG3 teamed up to (a) synthesize gold (Au) nanorods (length of ~110 nm, diameter of ~22 nm) and direct their assembly in lithographically-defined templates to form nanorod equilateral trimers. Axial displacement of the nanorods created “right-handed” (R) and left-handed (not shown) two-dimensional chiral enantiomers.
A Philadelphia school district high school teacher supported by the RET program in 2017 (Alexis Rylander Bennett, of Boys' Latin of Philadelphia Charter School) is now a full time researcher working with the Janmey lab for the summer and will continue when the school year starts again in Philadelphia. Image source: © Felice Macera
A Philadelphia school district high school teacher supported by the RET program in 2017 (Alexis Rylander Bennett, of Boys' Latin of Philadelphia Charter School) is now a full time researcher working with the Janmey lab for the summer and will continue when the school year starts again in Philadelphia. Image source: © Felice Macera
Nov 2, 2018
UPENN Materials Research Science and Engineering Centers

Structural Chemo-Mechanics of Fibrous Networks / Broader Impacts

David M. Chenoweth, Department of Chemistry, University of Pennsylvania

As part of our commitment to outreach, two students working with David Chenoweth in this IRG  (Alexander Kasznal and Samuel Melton) are involved in Spark mentoring programs. Spark Students are paired with a mentor based on mutual interests. Students visit their mentor’s workplace once a week for 10-13 weeks. Students experience the value of planning, implementation and practice with the creation of a Spark Project.
The plastic deformation of collagen fiber networks was assessed using fibroblast cell spheroids on collagen fiber networks. Second harmonic generation (blue) was used to quantify the persistence of fiber alignment between a pair of cell clusters (green). Persistence of fiber alignment was observed after cellular contractility was abolished using treatment with blebbistatin or trypsin.
The plastic deformation of collagen fiber networks was assessed using fibroblast cell spheroids on collagen fiber networks. Second harmonic generation (blue) was used to quantify the persistence of fiber alignment between a pair of cell clusters (green). Persistence of fiber alignment was observed after cellular contractility was abolished using treatment with blebbistatin or trypsin.
Nov 2, 2018
UPENN Materials Research Science and Engineering Centers

Mechanisms of Mechanical Plasticity in Collagen Networks from Contractile Forces

Primary Collaborators: Rebecca Wells (Medicine) and Vivek Shenoy (MRE) both members of the University of Pennsylvania MRSEC, IRG 2.

A collaboration (Wells, Shenoy) in IRG 2 studied the mechanisms of mechanical plasticity in collagen networks resulting from contractile forces produced by cellular aggregates placed within them. The Wells group used fibroblast spheroids seeded atop collagen gels to study the plasticity of collagen fiber networks due to cell-induced forces. Second harmonic generation imaging and spectral analysis enabled quantification of the alignment of fibers between a pair of contractile cell clusters.
Latin Charter Students in the Singh Center for Nanotechnology Cleanroom Image source: Felice Macera
Latin Charter Students in the Singh Center for Nanotechnology Cleanroom Image source: Felice Macera
Oct 26, 2018
UPENN Materials Research Science and Engineering Centers

Field Trip Series

Sophia Seifert & Mark Licurse , LRSM Education & Outreach, University of Pennsylvania

Starting in 2017, the LRSM and Singh Center for Nanotechnology hosted monthly field trips for Philadelphia middle and high school students. During these visits, students had introductory lessons on Materials Science and Nanotechnology and suited up for the clean room at the Quattrone Nanofabrication facility, where they observed and, when possible, assisted with lithography and soft-lithography. 124 students from four schools participated in the field trip program, of which 81% were URM and 96% were low-income (i.e., they qualify for the Federal Free and Reduced Lunch program).
Simulation of film structure (a) confirmed by electron diffraction (b). Real space experimental image (c) of film structure and simulated TEM image (d).
Simulation of film structure (a) confirmed by electron diffraction (b). Real space experimental image (c) of film structure and simulated TEM image (d).
Oct 26, 2018
UPENN Materials Research Science and Engineering Centers

Large-area synthesis of monolayer 1T'-WTe2 flakes

Andrew Rappe, Charlie Johnson, Rob Carpick, & Jay Kikkawa, Super Seed, University of Pennsylvania

Large-area growth of monolayer films of transition metal dichalcogenides is important in the rapidly advancing research field of topological materials, because scientists believe tungsten ditelluride has so-called “topological” electronic states. To this end, the Penn MRSEC SuperSeed team (Rappe, Johnson) and IRG faculty (Carpick, IRG-3; Kikkawa, IRG-4) collaborated to develop a growth process methodology for synthesis of reliable and reproducible large-area many-monolayer 1T'-WTe2 flakes.