Program Highlights

August 25, 2010

ImageRodlike fd viruses in an aqueous solution, along with polymers that produce an attractive force between the virus particles, have been observed in laboratory experiments to self-assemble into a variety of geometric structures including twisted ribbons (see the schematic illustration and microscope picture to the right). We have developed a theoretical model which explains the properties of these ribbons on the basis of very general features of the fd rods. The theory yields predictions in good agreement with experiment, namely, (a) a phase diagram with a first-order transition from flat membranes to twisted ribbons, (b) the ratio of the ribbon's pitch to width, (c) the tilt angle of the rods at the edge of the ribbon.  The theory has also demonstrated the importance of molecular chirality ("twisting-handedness") in the formation of the ribbons, as well as the tendency of fd rods to assemble into structures with negative Gaussian curvature (as in a saddle shape).

August 25, 2010

ImageCilia and flagella are tiny waving filaments with important functions in humans, such as clearing our airways. A 3D electron microscopy study of the normal (WT) and mutant varieties of flagella has revealed new details of the structure, protein composition, and connections between neighboring components formed by a crucial structural complex of this biological nanomachine, the "nexin-dynein regulatory complex" (N-DRC), which is shown in color on the left. In the poorly moving mutants, this structure is damaged or almost missing. This opens the way for building a new mechanical model of this device, and how it functions, along with mechanical testing of individual cilia and flagella, normal and mutant, in the Brandeis multi-mode optical microscopy laboratory. 

August 25, 2010

ImageDuring the academic year, Fall09 - Spring10, Dr. Kim, the facility director ,designed, built and tested devices for a number of MRSEC and outside users.

The application of semi-conductor processing technology to microfluidics permits the reduction of ordinary chemical laboratories to the size of a microprocessor chip, hence the name "lab-on-a-chip". One device that we have developed is called the Phase Chip which can store 1000 different samples in a square inch. Each sample contains 0.11 - 10 nanoliters of fluid and each compartment is in contact with a semi-permeable membrane which permits the rapid and reversible exchange of solvents. Our chip is designed for the study of liquid crystals, but we also have built chips for protein crystallization, a problem of importance to biology.

August 24, 2010

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A simple computational model demonstrates the assembly of self-limited filamentous bundles. The images are taken from dynamic Monte Carlo simulations in which "chiral" subunits ( with a preference to form twisted arrays of one "handedness") spontaneously assemble under different interaction strengths and degrees of chirality.

August 24, 2010

ImageStabilized emulsions containing the oscillating Belousov - Zhabotinsky chemical reaction (BZ) show interesting dynamics. Each drop acts as an independent chemical clock. However, they chemically communicate and exhibit collective behavior. In (a) six BZ drops are contained in a  capillary tube. The  white bars are light, which set the oscillators in the reduced state. Drops 1 & 6 are always exposed to light, setting the boundary conditions. Drops 3 & 4 are exposed to light for 0.5 periods. (b) A space time plot of the oscillations. White corresponds to the oxidized state; black to reduced. The drops adopt a dynamic oscillatory state predicted by theory. (c,d) Photograph and schematic, respectively, of experimental set-up. Study of these systems will elucidate a variety of chemically dynamic systems, ranging from neurons to Active Matter – polymeric systems which can convert chemical energy to mechanical motion.

August 23, 2010

Buehler and co-workers of the MIT MRSEC IRG-II have found that the key to silk's pound-for-pound toughness, which exceeds that of steel, is its beta-sheet crystals, the nano-sized cross-linking domains that hold the material together.

August 23, 2010

 


Shao-Horn and Hammond of the MIT MRSEC have found that using carbon nanotubes to fabricate a lithium battery’s electrodes produced a significant increase in the amount of power it could deliver, compared to a conventional lithium-ion battery.

 

 

August 18, 2010

  We have made the first experimental observation of the Aharonov-Bohm effect in neutral excitons. In classical mechanics the motion of an electrical charged particle is only affected if the particle enters a region of space with a magnetic or electric field. Meanwhile, in quantum physics, an electrically charged particle is affected by the magnetic potential in regions even if the magnetic and electric fields are zero in the region (Aharonov-Bohm effect). Several theory papers have discussed the plausible existence of the this effect even for neutral particles! We have confirmed this speculation.

August 18, 2010

We have achieved the colloidal growth of ZnSe doped (Cu and Mn) quantum dots. We demonstrate that doping chemistry of colloidal nanocrystals is much more complex than what has  been proposed in the existing experimental and theoretical reports. Four individual processes: “surface adsorption”, “lattice incorporation”, “lattice diffusion”, and “lattice ejection”. Each process possesses its own critical temperature. A given type of host nanocrystals can be switched from being impossible to dope to becoming successfully doped. The key is to program the reaction temperature to accommodate all elementary processes. The fluorescence shown here depends on size and dopant. 

August 16, 2010

Expanding outreach with portable SEM for K-12 math/science.

Last year MRSEC graduate students at the University of Arkansas brought cutting edge microscopy to local middle-school students and allow them to explore the world of nanoscience in real-time.   This year our focus expanded to regional high-school students. The microscope is a portable scanning electron microscope (SEM).   The SEM allows the students to explore the world of the “nano”.