Program Highlights

March 1, 2010

Block copolymer/nanoparticle (BCP/NP) composites have attracted interest because of the unique opportunities for tuning the properties of hybrid materials arising from the control of orientation and location of particle fillers within the copolymer matrix. However, quiescent organized block copolymer microstructures are not macroscopically uniform but rather exhibit ‘polycrystal-type’ texture with grain boundary defects that disrupt the long-range periodicity.

March 1, 2010

A collaboration between the CMU MRSEC and Sandia National Laboratory has permitted the first large scale comparison between experimentally measured grain boundary energies and energies calculated based on atomistic simulations. The techniques for the measurement (at CMU) and the calculations (Sandia) are unique to each institution and largest experimental and theoretical data sets currently available. The favorable comparison validates the methods.

February 26, 2010

thumbnail Cell Motility Driven by Actin PolymerizationIn designing new motile materials, much can be learned by studying the physical mechanisms underlying cell crawling. One important form of cell crawling is driven by self-assembly of the protein actin. In this process, energy is supplied and various proteins cooperate to assemble actin from small proteins into a branched network. We have conducted the first physically-consistent simulations of this process and have discovered that the mechanism driving motion of the cell boundary (modeled in our case by a flat disk) is very simple: the buildup of the branched actin network behind the disk drives the disk forwards because the disk is repelled by actin. This is reminiscent of the old joke about why bagpipe players always walk while they play (to get away from the noise). Understanding of this mechanism opens the way to the development of new materials that can move, such as asymmetrically-coated beads in self-generated concentration gradients.

February 18, 2010

A single electron spin in an external magnetic field forms a two-level system that can be used to create a spin qubit. However, achieving fast single spin rotations, as would be required to control a spin qubit, is a major challenge. It is difficult to drive spin rotations on timescales that are faster than the spin dephasing time and to individually address a single spin on the nanometer scale. We have developed a new method for quantum control of single spins that does not involve conventional electron spin resonance (ESR).

February 11, 2010

Silicon/silicon dioxide is arguably the most important technological interface. With the end of Moore’s law scaling for silicon fast approaching, alternatives to silicon dioxide could enable new electronic device architectures. MRSEC researchers have recently achieved ferroelectric functionality in intimate contact with silicon by growing SrTiO3 films in an intricate growth process using oxide molecular-beam epitaxy, producing fully strained SrTiO3 layers in direct contact with silicon with no interfacial silicon dioxide. Piezo-force microscopy sees ferroelectricity in the ultra-thin SrTiO3 layers. Stable ferroelectric nanodomains, observed at temperatures as high as 400 K, may form the basis of a new class of ferroelectric memories, bistable field-effect transistor devices, and low-power devices operating at room temperature.

February 11, 2010

The interplay between spin transport and exchange coupling profoundly affects charge transport between conventional metals and ferromagnets. This results in giant magnetoresistance and the spin valve effect in multilayer thin films, phenomena of great importance for magnetic data storage. MRSEC researchers have developed Co-Cu-Co multilayer nanowires to explore these phenomena in nanowire geometries. 

Element-sensitive scanning transmission electron microscopy reveals the composition of these multilayer nanowires. The thinnest Cu spacers produce a sizable 12% GMR at room temperature, consistent with interlayer exchange coupling. This coupling weakens with increasing Cu thickness, until a spin valve results. The evolution between these regimes provides new insights into spin diffusion in restricted geometries. 

February 9, 2010

magazine coverThe NYU team, led by Jasna Brujic, an assistant professor in NYU’s Department of Physics, developed an innovative way to tabulate the number of spheres-they created a method for determining how spheres pack from inside the jar, making it easier to more accurately count them.

To answer the question of how particles pack in general, the NYU researchers made a transparent, fluorescent packing of oil droplets in water, which allowed it to record three-dimensional images and examine the local geometry of each member of the pack. In other words, what does a packing look like from the point of view of a grain within-i.e., a “granocentric” view?