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Photochemically Mapping the Near-Fields of Plasmonic Nanocrescents

Objective: Use plasmon-enhanced photochemical reactions to map the polarization-dependent near fields of optical antennas. Approach: Use the anisotropic nano-crescent structure and SU-8 photo-resist. SU-8 exposure accomplished through plasmon-enhanced multi-photon absorption by 800 nm light. 

Approach: Use the anisotropic nano-crescent structure and SU-8 photo-resist. SU-8 exposure accomplished through plasmon-enhanced multi-photon absorption by 800 nm light. 

Results and Significance: Distinct anisotropic local-field patterns directly visualized through electron or AFM microscopy; patterns match simulation predictions. This is the first time field patterns of these structures have been mapped.

 

AFM image of gold nanocrescent structure.

 

 

SEM image of nanocrescent under short-axis excitation after SU-8 resist development; calculated field pattern below.

SEM image under long-axis excitation after resist development.