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Highlights

Under the right conditions, liquid crystals form astonishing structures reminiscent of biological systems, shown here in actual (left) and false color (right), with the filaments in light blue and the flattened discs in yellow. (Credit: Christopher Browne)
Under the right conditions, liquid crystals form astonishing structures reminiscent of biological systems, shown here in actual (left) and false color (right), with the filaments in light blue and the flattened discs in yellow. (Credit: Christopher Browne)
May 22, 2025
University of Pennsylvania

Self-Assembling Networks: A New Structured Fluid Architecture Through Phase Separation

Chinedum Osuji, University of Pennsylvania

Scientists at the University of Pennsylvania discovered a unique self-assembling network structure that forms when certain liquid crystal materials separate. These networks spontaneously create intricate patterns of filaments and disc-shaped structures through a series of physical transformations driven by competing forces.
Building Rigid Networks with Prestress and Selective Pruning
Building Rigid Networks with Prestress and Selective Pruning
May 22, 2025
Big Idea: Machine Learning / Artificial Intelligence

Building Rigid Networks with Prestress and Selective Pruning

John Crocker and Andrea Liu, University of Pennsylvania

Researchers John Crocker and Andrew Liu at the University of Pennsylvania have discovered that biopolymer networks pruned by tension-inhibited methods remain rigid at much lower coordinations than those pruned randomly. This finding helps explain the evolutionary advantage of tension-inhibited filament-severing proteins in biological systems.
Fast Ionic Conduction Achieved Through Ceramic Heterointerface Design
Fast Ionic Conduction Achieved Through Ceramic Heterointerface Design
May 22, 2025
University of Pennsylvania

Fast Ionic Conduction Achieved Through Ceramic Heterointerface Design

User of Scientific Experimental Facilities: Toyota Research Institute of North America

Toyota Research Institute of North America, collaborating with MRSEC-supported scientists and facilities have developed a novel [LiCl]/[FeOCl] heterointerface composite material (LFH) that achieves high lithium-ion conductivity from two traditionally non-conductive materials. The unique core-shell structure facilitates interstitial lithium-ion diffusion.
A free disclination imaged between cross polarizers at various strengths of the magnetic field indicated by the labels. Sample cell thickness is 15.9 mm. The dashed arcs are part of the best fit to the disclinations. Only part of the fit is shown for clarity. Scale bar in (a) is 500 mm and is the same for the other two images.
A free disclination imaged between cross polarizers at various strengths of the magnetic field indicated by the labels. Sample cell thickness is 15.9 mm. The dashed arcs are part of the best fit to the disclinations. Only part of the fit is shown for clarity. Scale bar in (a) is 500 mm and is the same for the other two images.
May 22, 2025
University of Pennsylvania

Measuring the Line Tension of Liquid Crystal Defects

Arjun Yodh, Jay Kikkawa, University of Pennsylvania; Peter Collings, Swarthmore

Researchers at the University of Pennsylvania and Swarthmore College developed new non-invasive methods to measure the mechanical properties of defects in liquid crystals using magnetic fields and advanced imaging. The study revealed that the line tension of twist disclinations ranges from 75 to 200 piconewtons and increases logarithmically with sample thickness, providing crucial quantitative data for testing theoretical models of these defects.
In contrast to the structured design (top), the more disordered one (bottom) cracked less easily, as evidenced by the dispersion of fracture events (red dots). (Credit: Sage Fulco)
In contrast to the structured design (top), the more disordered one (bottom) cracked less easily, as evidenced by the dispersion of fracture events (red dots). (Credit: Sage Fulco)
May 22, 2025
Big Idea: Machine Learning / Artificial Intelligence

Enhancing Fracture Toughness in Mechanical Metamaterials through Disorder

Kevin T. Turner and Doug Durian, U. Pennsylvania & Michal Budzik, Aarhus U.

MRSEC researchers at the University of Pennsylvania have demonstrated that introducing geometric disorder in mechanical metamaterials leads to distributed damage during failure, resulting in significantly enhanced fracture toughness with minimal loss of strength. This finding challenges the traditional reliance on periodic unit cell geometries in architected materials.
Large-Area Intercalated Two-Dimensional Pb/Graphene Heterostructure as a Platform for Generating Spin–Orbit Torque
Large-Area Intercalated Two-Dimensional Pb/Graphene Heterostructure as a Platform for Generating Spin–Orbit Torque
May 16, 2025
Pennsylvania State University

Large-Area Intercalated Two-Dimensional Pb/Graphene Heterostructure as a Platform for Generating Spin–Orbit Torque

Eli Rotenberg (LBNL), Nabil Bassim (MU), Adam Friedman (UM), Robert Wallac (UT Dallas), Chaoxing Liu, Nitin Samarth, Vincent Crespi, and Joshua Robinson

Researchers have successfully intercalated a stable monolayer of lead (Pb) into an experimental setup involving EG/SiC using a method that allows for detailed study of extremely thin heavy metal films. This technique enables higher coverage and better results than traditional methods. Notably, the lead layers show unique structural features and improved spin properties, indicating potential for new applications in spin transport phenomena. This finding highlights the promising use of Pb in creating innovative materials for future technologies.
Left: Computational phase map of rock salt HEO composition space quantified using the mixing enthalpy (ΔHmix) and standard deviation of bond lengths (σbonds).
Right: X-ray diffraction experimental with decreasing Ca% for Mg1/6Ca1/6Co1/6Ni1/6Cu1/6Zn1/6O. Black line shows a refined single-phase stability threshold.
Left: Computational phase map of rock salt HEO composition space quantified using the mixing enthalpy (ΔHmix) and standard deviation of bond lengths (σbonds). Right: X-ray diffraction experimental with decreasing Ca% for Mg1/6Ca1/6Co1/6Ni1/6Cu1/6Zn1/6O. Black line shows a refined single-phase stability threshold.
May 16, 2025
Pennsylvania State University

Discovering High-Entropy Oxides with a Machine-Learning Interatomic Potential

Sinnott, Maria, Rost (Virginia Tech), Chen

A research team has created a new method to discover high-entropy oxides (HEOs), which are materials with unique properties due to their disorder. They combined computer simulations and experiments to efficiently explore different HEO compositions. By using advanced machine-learning techniques, they accurately predicted the stability of various HEOs, leading to the discovery of a new type containing calcium. This approach will soon be used to investigate more complex crystal structures for potential new applications.
Permanent Dipole Moment in a Quantum-Confined Two-Dimensional Metal Revealed by Electric Double Layer Gating
Permanent Dipole Moment in a Quantum-Confined Two-Dimensional Metal Revealed by Electric Double Layer Gating
May 16, 2025
Pennsylvania State University

Permanent Dipole Moment in a Quantum-Confined Two-Dimensional Metal Revealed by Electric Double Layer Gating

Sawtarie (Pitt), Schrecengost (PSU), Ananthanarayanan (PSU), Manimaran (RIT), Awate (Pitt), Dong (PSU), Xu (RIT), Wang (U North Texas), Robinson (PSU), Giebink (PSU/U. Michigan) and Fullerton-Shirey (Pitt)

Researchers demonstrated that by applying electric fields to a two-dimensional gallium layer, they could detect a permanent dipole moment. This breakthrough, shown through microreflectivity, confirms earlier predictions about non-centrosymmetric bonding in 2D metals. The technique, called AC electric double layer gating, effectively modulates the material's properties, paving the way for new insights into the electronic structure and electro-optic characteristics of ultra-thin materials.
Discovery of Helical Inorganic Crystals as Building Blocks for Chiral and Non-reciprocal Excitations
Discovery of Helical Inorganic Crystals as Building Blocks for Chiral and Non-reciprocal Excitations
May 16, 2025
University of California, Irvine

Discovery of Helical Inorganic Crystals as Building Blocks for Chiral and Non-reciprocal Excitations

M. Arguilla, W. Ho, I. Krivorotov, E.M.Y. Lee, J. Romhanyi, and R. Wu (University of California, Irvine)

Researchers have developed a new method to create single crystals of a unique one-dimensional helical crystal called GaSI. This crystal has a distinctive "squircle" shape, combining square and circular features, which affects its properties. It also has a band gap of 3.7 eV and introduces a non-centrosymmetric unit cell, which leads to notable second harmonic generation. This work is significant for advancing our understanding of chiral materials and their optical and electronic behaviors.
Neural Network Kinetics: Exploring Diffusion Multiplicity and Chemical Ordering in Compositionally Complex Materials
Neural Network Kinetics: Exploring Diffusion Multiplicity and Chemical Ordering in Compositionally Complex Materials
May 16, 2025
University of California, Irvine

Neural Network Kinetics: Exploring Diffusion Multiplicity and Chemical Ordering in Compositionally Complex Materials

B. Xing, W. Zou, T.J. Rupert, X.Q. Pan, and P. Cao (University of California, Irvine)

A new neural network-based method called Neural Network Kinetics (NNK) has been developed to predict how chemicals and structures change over time in complex environments. This technique effectively models atom movements and diffusion barriers. Researchers applied NNK to study the NbMoTa alloy, discovering a key temperature where a specific chemical order peaks. They found significant variations in atom mobility near this temperature, which are crucial for understanding chemical ordering and the formation of the B2 structure.