In this highlight, researchers at the University of Chicago MRSEC report the development of a polymeric, pluripotent material that can be tempered (akin to the process in metallurgy) to access a wide range of room temperature mechanical properties, from stiff and high strength to soft and extensible, from a single feedstock. The feedstock was composed of a benzalcyanoacetate-based Michael acceptor, a tetrathiol crosslinker, and a dithiol chain extender to form dynamic thia-Michael networks.