We have identified a composition in Sm doped BiFeO3 which exhibits a complex mixture of ferroelectric phase and an antiferroelectric phase. Left shows a high resolution TEM image of a region displaying an interface between a rhombohedral ferroelectric phase (FE matrix) and antiferroelectric (antipolar clusters).

Magnetism is typically associated with “transition metal” elements such as nickel or iron, from the middle of the periodic table.  These elements contain d electrons which are localized on the atoms, and have a “spin” or magnetic moment.  Carbon contains no d electrons and is not normally magnetic. 

Graphene (two-dimensional carbon) is an attractive material for spintronics due to weak spin-orbit coupling for robust spin transport properties. This could lead to spin-based computers that integrate logic and memory for much greater computing power.

Ordered double perovskites, such as Sr2FeMoO6, are among the very few materials that allow electrons of one spin direction to move through them as though they were passing through a normal metal, while blocking electrons of the opposite spin.  Materials that behave this way at room temperature are even more exotic.

Modern electronics, e.g. a smart phone, relies heavily on science and engineering: semiconductors (diodes, transistors), magnetism (hard drives), photoelectric effect (digital camera), photon generation and lasers (LEDs, CD/DVD drives), light polarization (LCD), etc. The immediacy and applicability makes electronics a great tool for teaching science and technology.

Part of the CRISP Shared Equipment is a unique variable temperature, variable magnetic field ultrahigh vacuum scanning force microscope for applications in magnetic, electrostatic, piezoelectric, and friction force microscopy. • One chamber vacuum system• Entirely homebuilt, students played a key role in designing, building, and testing• Enables investigations of local ferromagnetic and ferroelectric properties of complex oxide multiferroic material near their transition temperatures

The goal of CRISP professional development workshops is to improve the quality and diversity of STEM education for science teachers in neighboring urban school districts. CRISP offers inquiry-based workshops which utilize CRISP specialized research facilities to emphasize the interdisciplinary nature of materials science and nanotechnology. Workshops have been offered to more than 100 participants to date.

The unique properties of transition metal oxides allow electrons to be manipulated in new ways. At CRISP, we have created an oxide device that enables a gas of electrons to be expanded or compressed with an applied electric field. The expansion or compression of the gas modulates the speed of moving electrons. The change in the speed of the electrons could be utilized in high speed transistors.

Many species of birds have feathers with colors that are the result of light scattering from a disordered arrangement of nanoscale air spheres. The feathers appear to be the same color from every angle. Inspired by these beautiful feathers, we design structures of polymer nanoparticles that produce color the same way. This is a new way to make color from nanostructures and could be useful for textiles, coatings, and cosmetics.

A multi-partner collaborative effort has focused on understanding semiconductor-oxide interfaces.  This involves atomic layer precision in synthesis of the structures, correlating the structure and electronic properties using first principles, and obtaining subatomic resolution of structures from synchrotron x-ray diffraction a the Advanced Photon Source (Argonne National Laboratory) and electron micrsocopy (Brookhaven National Laboratory).  The outcomes of these studies are critical for the design of ferroelectric field effect transistors.